barbiturates in general would be substances usable for this. sleep enforcing effects
can also be expected from (non-)benzodiazepines (midazolam, diazepam, brotizolam,
estazolam, flunitrazepam, flutoprazepam, loprazolam, lormetazepam, nimetazepam, nitrazepam, quazepam, triazolam, zaleplon, zolpidem, zopiclone, ...) quinazolinones (methaqualone, methylmethaqualone,
diproqualone, etaqualone, mebroqualone, mecloqualone, nitromethaqualone, SL-164)
antidepressants (mirtazapine, ketamine, trazodone, trimipramine, doxepin, mianserin) and
especially potent sleeping pills (clomethiazole).
of the above lormetazepam plus clomethiazole can be obtained from Spain without prescription.
based on my self-test, approx. 900ml of vodka, which contained 37% alcohol, have been enough to make me pass out. alcohol is another option.
what if you can't stand the aggressive character of it that burns your throat and makes alcohol rather difficult to swallow? instead of drinking it all, you could fill (some of) it into capsules. they are available in different sizes. 000 is the largest with a bit over 1mg or ml capacity. size 00, however, is all you can acquire if vegan (= gelatin free) capsules are required. they hold exactly 1mg or ml.
unfortunately, they aren't meant for liquids but for powder or something non-liquid akin to it. alcohol will cause them to fall apart eventually. after around 15mins.
you'll be able to find 96 percentaged ethanol/ethyl alcohol. around 347 capsules, sized 00, filled with 96% ethanol (you can use a syringe for that procedure) is what you'd need to approximate 900ml vodka.
it is unlikely that anyone would manage to prepare and right away consume such a large amount before the liver has metobolized enough of it to increase the need for an even larger dose in order to become unconscious.
"metabolism is the body's process of converting ingested substances to other compounds. metabolism results in some substances becoming more, and some less, toxic than those originally ingested"
-http://pubs.niaaa.nih.gov/publications/aa35.htm
in the case of alcohol, metabolism leads to alcohol becoming less toxic, less effective in causing poisoning/enforced sleep. "the liver can metabolize only a certain amount of alcohol per hour, regardless of the amount that has been consumed. the rate of alcohol metabolism depends, in part, on the amount of metabolizing enzymes in the liver, which varies among individuals"
"in general, after the consumption of one standard drink, the amount of alcohol in the drinker's blood (blood alcohol concentration, or BAC) peaks within 30 to 45 minutes."
-http://pubs.niaaa.nih.gov/publications/aa35.htm
but with large doses, it can take a whole hour before you reach full drunkenness. then the blood alcohol concentration declines. you'd therefore want to get over with it all within around 1 hour. some capsules you will be able to prepare, some alcohol you would need to drink conventionally.
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